Journal of Multidisciplinary Applied Natural Science
Open Access Journal
Scopus CiteScore 2024
4.8
Calculated on 05 May, 2025
SJR 2024
0.31
Powered by scimagojr.com
Open Access Journal
4.8
Calculated on 05 May, 2025
0.31
Powered by scimagojr.com
https://doi.org/10.47352/jmans.2774-3047.90
Rodhiansyah Djayasinga
Andi Setiawan
Chicken eggshell waste is a promising source of CaO which can be converted into heterogeneous catalyst materials. The purpose of this study was to utilize CaO heterogeneous catalyst derived from breed chicken eggshell to produce biodiesel from waste cooking oil through the transesterification process. A total of 4 g of catalyst material was mixed with 200 g of waste cooking oil and 60 g of methanol, and then the mixture was stirred at a speed of 700 rpm for 6 h at 60 ± 40C. The produced biodiesel was analyzed using GC-MS to elucidate the various methyl ester compounds. The produced biodiesel was found to have a density of 855 kg/m3, viscosity of 3.74 mm2/s (cSt), and flash point of 135 0C. Based on these results, it can be concluded that breed chicken eggshells are potential sources for the preparation of CaO catalyst material to produce biodiesel from waste cooking oil. This finding is very useful for further optimization of mass catalysts heterogeneous CaO from breed chicken eggshells including the commercial production of biodiesel.
[1] F. Nadeem, I. A. Bhatti, A. Ashar, M. Yousaf, M. Iqbal, M. Mohsin, J. Nisar, N. Tamam, and N. Alwadai. (2021). “Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach”. Arabian Journal of Chemistry. 14 (8): 103263. 10.1016/j.arabjc.2021.103263.
DOI: https://doi.org/10.1016/j.arabjc.2021.103263[2] J. Liu, M. Liu, S. Chen, B. Wang, J. Chen, D.-P. Yang, S. Zhang, and W. Du. (2020). “Conversion of Au(III)-polluted waste eggshell into functional CaO/Au nanocatalyst for biodiesel production”. Green Energy & Environment. 10.1016/j.gee.2020.07.019.
DOI: https://doi.org/10.1016/j.gee.2020.07.019[3] P. Maneechakr and S. Karnjanakom. (2021). “Systematic production of biodiesel fuel from palm oil over porous K2O@CaO catalyst derived from waste chicken eggshell via RSM/kinetic/thermodynamic studies”. Journal of Environmental Chemical Engineering. 9 (6): 106542. 10.1016/j.jece.2021.106542.
DOI: https://doi.org/10.1016/j.jece.2021.106542[4] M. Khatibi, F. Khorasheh, and A. Larimi. (2021). “Biodiesel production via transesterification of canola oil in the presence of Na–K doped CaO derived from calcined eggshell”. Renewable Energy. 163 : 1626–1636. 10.1016/j.renene.2020.10.039.
DOI: https://doi.org/10.1016/j.renene.2020.10.039[5] F. Yaşar. (2019). “Biodiesel production via waste eggshell as a low-cost heterogeneous catalyst: Its effects on some critical fuel properties and comparison with CaO”. Fuel. 255 : 115828. 10.1016/j.fuel.2019.115828.
DOI: https://doi.org/10.1016/j.fuel.2019.115828[6] K. D. Pandiangan and W. Simanjuntak. (2013). “Transesterification of coconut oil using dimethyl carbonate and TiO2/SiO2 heterogeneous catalyst”. Indonesian Journal of Chemistry. 13 (1): 47–52. 10.22146/ijc.21325.
DOI: https://doi.org/10.22146/ijc.21325[7] A. Bavykina, N. Kolobov, I. S. Khan, J. A. Bau, A. Ramirez, and J. Gascon. (2020). “Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives”. Chemical Reviews. 120 (16): 8468–8535. 10.1021/acs.chemrev.9b00685.
DOI: https://doi.org/10.1021/acs.chemrev.9b00685[8] J. Zhong, X. Yang, Z. Wu, B. Liang, Y. Huang, and T. Zhang. (2020). “State of the art and perspectives in heterogeneous catalysis of CO2 hydrogenation to methanol”. Chemical Society Reviews. 49 (5): 1385–1413. 10.1039/C9CS00614A.
DOI: https://doi.org/10.1039/C9CS00614A[9] C. Xie, D. Yan, H. Li, S. Du, W. Chen, Y. Wang, Y. Zou, R. Chen, S. Wang. (2020). “Defect Chemistry in Heterogeneous Catalysis: Recognition, Understanding, and Utilization”. ACS Catalysis. 10 (19): 11082–11098. 10.1021/acscatal.0c03034.
DOI: https://doi.org/10.1021/acscatal.0c03034[10] S. Palitsakun, K. Koonkuer, B. Topool, A. Seubsai, and K. Sudsakorn. (2021). “Transesterification of Jatropha oil to biodiesel using SrO catalysts modified with CaO from waste eggshell”. Catal. Commu Catalysis Communications. 149 : 106233. 10.1016/j.catcom.2020.106233.
DOI: https://doi.org/10.1016/j.catcom.2020.106233[11] Z. L. Chung, Y. H. Tan, Y. S. Chan, J. Kansedo, N. M. Mubarak, M. Ghasemi, M. O. Abdullah. (2019). “Life cycle assessment of waste cooking oil for biodiesel production using waste chicken eggshell derived CaO as catalyst via transesterification”. Biocatalysis and Agricultural Biotechnology. 21 : 101317. 10.1016/j.bcab.2019.101317.
DOI: https://doi.org/10.1016/j.bcab.2019.101317[12] H. Hadrah, M. Kasman, and F. M. Sari. (2018). “Analisis Minyak Jelantah Sebagai Bahan Bakar Biodiesel dengan Proses Transesterifikasi”. Jurnal Daur Lingkungan. 1 (1): 16. 10.33087/daurling.v1i1.4.
DOI: https://doi.org/10.33087/daurling.v1i1.4[13] Y. S. Kurniawan, K. T. A. Priyangga, P. A. Krisbiantoro, and A. C. Imawan. (2021). “Green Chemistry Influences in Organic Synthesis : a Review”. Journal of Multidisciplinary Applied Natural Science. 1 (1): 1–12. 10.47352/jmans.v1i1.2.
DOI: https://doi.org/10.47352/jmans.v1i1.2[14] A. Fadaka, O. Aluko, S. Awawu, and K. Theledi. (2021). “Green Synthesis of Gold Nanoparticles using Pimenta dioica Leaves Aqueous Extract and Their Application as Photocatalyst, Antioxidant, and Antibacterial Agents”. Journal of Multidisciplinary Applied Natural Science. 1 (2): 78–88. 10.47352/jmans.v1i2.81.
DOI: https://doi.org/10.47352/jmans.v1i2.81[15] A. Nurain, P. Sarker, M. S. Rahaman, M. M. Rahman, and M. K. Uddin. (2021). “Utilization of Banana (Musa sapientum) Peel for Removal of Pb2+ from Aqueous Solution”. Journal of Multidisciplinary Applied Natural Science. 1 (2): 117–128. 10.47352/jmans.v1i2.89.
DOI: https://doi.org/10.47352/jmans.v1i2.89[16] J. Zhang, F. Cui, L. Xu, X. Pan, X. Wang, X. Zhang, T. Cui. (2017). “The development of novel Au/CaO nanoribbons from bifunctional building block for biodiesel production”. Nanoscale. 9 (41): 15990–15997. 10.1039/c7nr04890d.
DOI: https://doi.org/10.1039/C7NR04890D[17] J. Yan, X. Zheng, and S. Li. (2014). “A novel and robust recombinant Pichia pastoris yeast whole cell biocatalyst with intracellular overexpression of a Thermomyces lanuginosus lipase: Preparation, characterization and application in biodiesel production”. Bioresource Technology. 151 : 43–48. 10.1016/j.biortech.2013.10.037.
DOI: https://doi.org/10.1016/j.biortech.2013.10.037[18] E. Alptekin, M. Canakci, and H. Sanli. (2014). “Biodiesel production from vegetable oil and waste animal fats in a pilot plant”. Waste Management. 34 (11): 2146–2154. 10.1016/j.wasman.2014.07.019.
DOI: https://doi.org/10.1016/j.wasman.2014.07.019[19] Y. Dang, X. Luo, F. Wang, and Y. Li. (2016). “Value-added conversion of waste cooking oil and post-consumer PET bottles into biodiesel and polyurethane foams”. Waste Management. 52 : 360–366. 10.1016/j.wasman.2016.03.054.
DOI: https://doi.org/10.1016/j.wasman.2016.03.054[20] Y. Xiong, W. F. Miao, N. N. Wang, H. M. Chen, X. R. Wang, J. Y. Wang, Q. L. Tan, S. P. Chen. (2019). “Solid alcohol based on waste cooking oil: Synthesis, properties, micromorphology and simultaneous synthesis of biodiesel”. Waste Management. 85 : 295–303. 10.1016/j.wasman.2018.12.036.
DOI: https://doi.org/10.1016/j.wasman.2018.12.036[21] J. M. Marchetti. (2012). “A summary of the available technologies for biodiesel production based on a comparison of different feedstock’s properties”. Process Safety and Environmental Protection. 90 (3): 157–163. 10.1016/j.psep.2011.06.010.
DOI: https://doi.org/10.1016/j.psep.2011.06.010[22] M. Agarwal, G. Chauhan, S. P. Chaurasia, and K. Singh. (2012). “Study of catalytic behavior of KOH as homogeneous and heterogeneous catalyst for biodiesel production”. Journal of the Taiwan Institute of Chemical Engineers. 43 (1): 89–94. 10.1016/j.jtice.2011.06.003.
DOI: https://doi.org/10.1016/j.jtice.2011.06.003[23] S. M. Pavlović, D. M. Marinković, M. D. Kostić, I. M. Janković-Častvan, L. V. Mojović, M. V. Stanković, V. B. Veljković. (2020). “A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production”. Fuel. 267 : 117171. 10.1016/j.fuel.2020.117171.
DOI: https://doi.org/10.1016/j.fuel.2020.117171[24] A. A. Ayodeji, O. E. Modupe, B. Rasheed, and J. M. Ayodele. (2018). “Data on CaO and eggshell catalysts used for biodiesel production”. Data in Brief. 19 : 1466–1473. 10.1016/j.dib.2018.06.028.
DOI: https://doi.org/10.1016/j.dib.2018.06.028[25] S. Susumu, R. Rusdianasari, and S. Yusi. (2018). “Biodiesel Production from Waste Cooking Oil using Electrostatic Method”. Indonesian Journal of Fundamental and Applied Chemistry. 3 (3): 71–76. 10.24845/ijfac.v3.i3.71.
DOI: https://doi.org/10.24845/ijfac.v3.i3.71[26] A. Santoso, Sumari, U. Urfa Zakiyya, and A. Tiara Nur. (2019). “Methyl Ester Synthesis of Crude Palm Oil Off Grade Using the K2O/Al2O3 Catalyst and Its Potential as Biodiesel” IOP Conference Series: Materials Science and Engineering. 515 : 012042. 10.1088/1757-899X/515/1/012042.
DOI: https://doi.org/10.1088/1757-899X/515/1/012042[27] H. Amrulloh, A. Fatiqin, W. Simanjuntak, H. Afriyani, and A. Annissa. (2021). “Antioxidant and Antibacterial Activities of Magnesium Oxide Nanoparticles Prepared using Aqueous Extract of Moringa Oleifera Bark as Green Agents”. Journal of Multidisciplinary Applied Natural Science. 1 (1): 44–53. 10.47352/jmans.v1i1.9.
DOI: https://doi.org/10.47352/jmans.v1i1.9